| - Germany (2), Netherlands (3), England (4) and Spain (5) exempt until Round 3 of World League Men 2014 as ranked among first 8 teams in World Ranking. | | - Belgium (13) exempt until Round 2 of World League Men 2014 as ranked among first 16 teams in World Ranking. | | - France and Russia exempt until Round 2 of World League Men 2014 as Host of Round 2 Tournamets. | | - Azerbaijan and Turkey were put in West Asia Group Asia Men WL 2012. |
| All other teams played in | | Group I | Praga (CZE) | Poland | Ukraine | Belarus | Czechia | | | Group II | Cardiff (WAL) | Ireland | Austria | Wales | Sweden | | | Group III | Lousada (POR) | Scotland | Portugal | Gibraltar | Italy | Morocco |
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| Poland, Ukraine, Ireland, Austria, Scotland and Portugal passed to Second Round of World League Men 2014. |
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| Group I | p | w | l | gf | ga | | 1. Poland | 9 | 3 | 0 | 10: | 2 | | 2. Ukraine | 5 | 1+1 | 1 | 8: | 12 | | 3. Belarus | 3 | 1 | 2 | 6: | 8 | | 4. Czechia | 1 | 0 | 1+2 | 6: | 8 |
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| Team | Pola | Ukra | Bela | Czec | | Poland | --- | 5:0 | 2:0 | 3:2 | | Ukraine | | --- | 5:4 | 3:3 | | Belarus | | | --- | 2:1 | | Czechia | | | | --- |
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| date | venue | team 1 | score | team 2 | HT | | | played in Praga (CZE) UTC +02:00 | | 17.08 | 14:45 |  Poland | 5-0 |  Ukraine | 3-0 | Goals | | 17.08 | 17:00 |  Belarus | 2-1 |  Czechia | 1-0 | Goals | | 18.08 | 14:45 | Ukraine | 5-4 | Belarus | 3-1 | Goals | | 18.08 | 17:00 | Poland | 3-2 | Czechia | 2-1 | Goals | | 19.08 | 14:45 | Poland | 2-0 | Belarus | 2-0 | Goals | | 19.08 | 17:00 | Ukraine | 3-3 | Czechia | 0-2 | Goals | | penalties 3-2 |
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| Best Player: Artem Ozerskyy (UKR) | | Fair Play: Belarus |
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| Group II | p | w | d | l | gf | ga | | 1. Ireland | 9 | 3 | 0 | 0 | 18: | 1 | | 2. Austria | 5 | 1 | 1 | 1 | 6: | 6 | | 3. Wales | 4 | 1 | 1 | 1 | 4: | 5 | | 4. Sweden | 0 | 0 | 0 | 3 | 1: | 17 |
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| Team | Irel | Aust | Wale | Swed | | Ireland | --- | 5:1 | 5:0 | 8:0 | | Austria | | --- | 0:0 | 5:1 | | Wales | | | --- | 4:0 | | Sweden | | | | --- |
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| date | venue | team 1 | score | team 2 | HT | | | played in Cardiff (WAL) UTC +01:00 | | 07.09 | 15:30 |  Austria | 5-1 |  Sweden | 3-1 | Goals | | 07.09 | 18:00 |  Ireland | 5-0 |  Wales | 2-0 | Goals | | 08.09 | 14:00 | Ireland | 5-1 | Austria | 2-0 | Goals | | 08.09 | 18:30 | Wales | 4-0 | Sweden | 1-0 | Ireland | 8-0 | Sweden | 3-0 | Goals | | 09.09 | 15:00 | Austria | 0-0 | Wales | 0-0 | | | shoot-out 4-3 |
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| Group III | p | w | l | gf | ga | | 1. Scotland | 12 | 4 | 0 | 30: | 0 | | 2. Portugal | 8 | 2+1 | 1 | 13: | 13 | | 3. Gibraltar | 6 | 1+1 | 1+1 | 7: | 11 | | 4. Italy | 4 | 1 | 1+2 | 7: | 16 | | 5. Morocco | 0 | 0 | 4 | 1: | 18 |
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| Team | Scot | Port | Gibr | Ital | Moro | | Scotland | --- | 7:0 | 5:0 | 9:0 | 9:0 | | Portugal | | --- | 3:3 | 4:2 | 6:1 | | Gibraltar | | | --- | 3:3 | 1:0 | | Italy | | | | --- | 2:0 | | Morocco | | | | | --- |
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| date | venue | team 1 | score | team 2 | HT | | | played in Lousada (POR) UTC + 01:00 | - | | 25.09 | 14:30 |  Gibraltar | 1-0 | Morocco | 1-0 | Goal | | 26.09 | 14:30 |  Scotland | 9-0 | Morocco | 3-0 | Goals | | 26.09 | 16:45 | Gibraltar | 3-3 |  Italy | 2-1 | | | Shoot-out 3-1 Goals | | 27.09 | 14:30 | Scotland | 5-0 | Gibraltar | 1-0 | Goals | | 27.09 | 16:45 |  Portugal | 6-1 | Morocco | 3-1 | Goals | | 28.09 | 11:00 | Portugal | 4-2 | Italy | 2-1 | Goals | | 29.09 | 14:00 | Italy | 2-0 | Morocco | 0-0 | Goals | | 29.09 | 16:15 | Scotland | 7-0 | Portugal | 5-0 | Goals | | 30.09 | 13:00 | Scotland | 9-0 | Italy | 3-0 | Goals | | 30.09 | 15:30 | Portugal | 3-3 | Gibraltar | 2-0 | | | Shoot-Out 2-0 Goals |
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