| - Netherlands (2), Germany (3) and England (5) exempt until Round 3 of World League Women 2014 as ranked among first 8 teams in World Ranking. | | - Spain (10), Azerbaijan (14) and Ireland (15) exempt until Round 2 of World League Women 2014 as ranked among first 16 teams in World Ranking. |
| All other teams played in | | Group I | Praga (CZE) | Belarus | Italy | Scotland | Czechia | France | Turkey | | Group II | Wien (AUT) | Belgium | Russia | Ukraine | Austria | Lithuania | Wales |
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| Belarus, Italy, Scotland, Czechia, Belgium, Russia, Ukraine and Austria passed to Second Round of World League Women 2014. |
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| Group I | p | w | d | l | gf | ga | | 1. Belarus | 12 | 4 | 0 | 1 | 33: | 6 | | 2. Italy | 12 | 4 | 0 | 1 | 25: | 2 | | 3. Scotland | 12 | 4 | 0 | 1 | 23: | 5 | | 4. Czechia | 6 | 2 | 0 | 3 | 17: | 16 | | 5. France | 3 | 1 | 0 | 4 | 4: | 25 | | 6. Turkey | 0 | 0 | 0 | 5 | 2: | 50 |
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| Team | Bela | Ital | Scot | Czec | Fran | Turk | | Belarus | ---- | 2:1 | | 4:2 | 9:1 | 17:0 | | Italy | | ---- | 2:0 | 6:0 | 6:0 | 10:0 | | Scotland | 2:1 | | ---- | 5:1 | 4:0 | 12:1 | | Czechia | | | | ---- | 5:1 | 9:0 | | France | | | | | ---- | 2:1 | | Turkey | | | | | | ---- |
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| date | time | team 1 | score | team 2 | HT | | | played in Praga (CZE) UTC +02:00 | | 14.08 | 12:30 |  Scotland | 12-1 |  Turkey | 6-0 | Goals | | 14.08 | 14:45 |  Belarus | 9-1 |  France | 5-0 | Goals | | 14.08 | 17:00 |  Italy | 6-0 |  Czechia | 1-0 | Goals | | 15.08 | 12:30 | Belarus | 17-0 | Turkey | 6-0 | Goals | | 15.08 | 14:45 | Italy | 6-0 | France | 2-0 | Goals | | 15.08 | 17:00 | Scotland | 5-1 | Czechia | 4-0 | Goals | | 16.08 | 12:30 | Italy | 10-0 | Turkey | 5-0 | Goals | | 16.08 | 14:45 | Scotland | 2-1 | Belarus | 1-1 | Goals | | 16.08 | 17:00 | Czechia | 5-1 | France | 3-1 | Goals | | 18.08 | 08:00 | France | 2-1 | Turkey | 1-1 | Goals | | 18.08 | 10:15 | Italy | 2-0 | Scotland | 0-0 | Goals | | 18.08 | 12:30 | Belarus | 4-2 | Czechia | 2-0 | Goals | | 19.08 | 08:00 | Scotland | 4-0 | France | 1-0 | Goals | | 19.08 | 10:15 | Belarus | 2-1 | Italy | 0-1 | Goals | | 19.08 | 12:30 | Czechia | 9-0 | Turkey | 5-0 | Goals |
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| Best Player: Chiara Tiddi (ITA) | | Fair Play: France |
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| Group II | p | w | d | l | gf | ga | | 1. Belgium | 15 | 5 | 0 | 0 | 19: | 5 | | 2. Russia | 12 | 4 | 0 | 1 | 11: | 7 | | 3. Ukraine | 9 | 3 | 0 | 2 | 8: | 8 | | 4. Austria | 4 | 1 | 1 | 3 | 5: | 8 | | 5. Lithuania | 4 | 1 | 1 | 3 | 3: | 12 | | 6. Wales | 0 | 0 | 0 | 5 | 1: | 7 |
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| Team | Belg | Russ | Ukra | Aust | Lith | Wale | | Belgium | --- | 4:2 | 4:0 | 2:1 | 7:1 | 2:1 | | Russia | | --- | 3:2 | 2:1 | 2:0 | 2:0 | | Ukraine | | | --- | 3:1 | 2:0 | 1:0 | | Austria | | | | --- | 1:1 | 1:0 | | Lithuania | | | | | --- | 1:0 | | Wales | | | | | | --- |
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| date | time | team 1 | score | team 2 | HT | | | 18.09 | 12:30 |  Belgium | 7-1 | Lithuania | 3-1 | Goals | | 18.09 | 14:45 |  Ukraine | 1-0 |  Wales | 1-0 | Goal | | 18.09 | 14:45 |  Russia | 2-1 |  Austria | 1-0 | Goals | | 19.09 | 12:30 | Ukraine | 2-0 | Lithuania | 1-0 | Goals | | 19.09 | 14:45 | Russia | 2-0 | Wales | 2-0 | Goals | | 19.09 | 17:00 | Belgium | 2-1 | Austria | 1-1 | Goals | | 20.09 | 12:30 | Russia | 2-0 | Lithuania | 2-0 | Goals | | 20.09 | 14:45 | Belgium | 4-0 | Ukraine | 1-0 | Goals | | 20.09 | 17:00 | Austria | 1-0 | Wales | 0-0 | Goal | | 22.09 | 12:30 | Belgium | 4-2 | Russia | 2-1 | Goals | | 22.09 | 14:45 | Lithuania | 1-0 | Wales | 1-0 | Goal | | 22.09 | 17:00 | Ukraine | 3-1 | Austria | 2-1 | Goals | | 23.09 | 12:30 | Belgium | 2-1 | Wales | 0-0 | Goals | | 23.09 | 14:45 | Russia | 3-2 | Ukraine | 1-0 | Goals | | 23.09 | 17:00 | Austria | 1-1 | Lithuania | 1-0 | | | Shoot-Out: 4-3 Goals |
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