| date | Pair 1 | sets | Pair 2 | set 1 | set 2 | TB | dur. | 
| Thu 11.08.16 | Heather Watson / Andy Murray |  GBR |   | 2-0 | Carla Suarez Navarro / David Ferrer |  ESP |   | 6-3 | 6-3 |   | 1:16 | 
| Thu 11.08.16 | Teliana Pereira / Marcelo Melo |  BRA |   | 2-0 | Caroline Garcia / Nicolas Mahut |  FRA |   | 6-74 | 7-61 |   | 1:56  | 
| Thu 11.08.16 | Sania Mirza / Rohan Bopanna |  IND |   | 2-0 | Samantha Stosur / John Peers |  AUS |   | 7-5 | 6-4 |   | 1:13  | 
| Thu 11.08.16 | Venus Williams / Rajeev Ram |  USA |   | 2-1 | Kiki Bertens / Jean-Julien Rojer |  NED |   | 6-74 | 7-63 | [10-8] | 1:57  | 
| Thu 11.08.16 | Bethanie Matek-Sands / Jack Sock |  USA |   | 2-0 | Johanna Konta / Jamie Murray |  GBR |   | 6-4 | 6-3 |   | 1:17  | 
| Thu 11.08.16 | Irina-Camelia Begu / Horia Tecau |  ROU |   | 2-1 | Agnieszka Radwanska / Lukasz Kubot |  POL |   | 4-6 | 7-61 | [10-8] | 1:48  | 
| Thu 11.08.16 | Roberta Vinci / Fabio Fognini |  ITA |   | 2-1 | Kristina Mladenovic / Pierre-Hugues Herbert |  FRA |   | 6-4 | 3-6 | [10-8] | 1:10  | 
| Thu 11.08.16 | Lucie Hradecka / Radek Stepanek |  TCH |   | wo | Garbine Muguruza / Rafael Nadal |  ESP |   | Muguruza / Nadal withdrew |