| date | Pair 1 | sets | Pair 2 | set 1 | set 2 | set 3 | dur (points) |
| Sat 05.02.20 | Jean-Julien Rojer / Horia Tecau |  NED |  ROU | | 2-1 | Juan Sebastian Cabal / Robert Farah |  COL | COL | 1 | 4-6 | 6-3 | 6-4 | 2:01 (93-85) |
| Sat 05.02.20 | Rohan Bopanna / Denis Shapovalov |  IND |  CAN | | 2-1 | Kevin Krawietz / Andreas Mies |  GER | GER | 6 | 4-6 | 6-4 | 6-3 | 1:50 (92-87) |
| Sat 05.02.20 | Jamie Murray / Neal Skupski |  GBR | GBR | | 2-0 | Marcelo Demoliner / Matwe Middelkoop |  BRA | NED | | 6-3 | 6-2 | | 1:10 (65-43) |
| Sat 05.02.20 | Mate Pavic / Bruno Soares |  CRO | BRA | | 2-1 | Jack Sock / Jack Withrow |  USA | USA | | 5-7 | 7-65 | 6-4 | 2:05 (108-105) |
| Fri 04.02.20 | Christopjer Eubanks / Mackenzie McDonald | USA | USA | WC | 2-0 | Marcus Daniell / Philipp Oswald |  NZL |  AUT | | 7-65 | 6-3 | | 1:24 (69-60) |
| Fri 04.02.20 | Rajeev Ram / Joe Salisbury | USA | GBR | 3 | 2-0 | Christian Harrison / Ryan Harrison | USA | USA | WC | 6-2 | 6-4 | | 1:08 (61-45) |
| Fri 04.02.20 | Wesley Koolhof / Nikola Mektic | NED | CRO | 8 | 2-0 | Simone Bolelli / Maximo Gonzalez |  ITA |  ARG | | 6-4 | 6-3 | | 1:28 (69-56) |
| Fri 04.02.20 | Sander Gille / Joran Vliegen |  BEL | BEL | | 2-0 | John Peers / Michael Venus |  AUS | NZL | | 6-4 | 6-4 | | 1:16 (63-53) |
| date | Pair 1 | sets | Pair 2 | set 1 | set 2 | set 3 | dur (points) |
| Thu 03.02.20 | Juan Sebastian Cabal / Robert Farah | COL | COL | 1 | 2-0 | Jurgen Melzer / Edouard Roger-Vasselin | AUT |  FRA | | 6-2 | 6-3 | | 1:01 (57-38) |
| Thu 03.02.20 | Jean-Julien Rojer / Horia Tecau | NED | ROU | | 2-1 | Marcelo Arevalo / Jonny O'Mara |  ESA | GBR | | 6-73 | 6-2 | 6-4 | 2:11 (107-87) |
| Fri 04.02.20 | Rohan Bopanna / Denis Shapovalov | IND | CAN | | 2-0 | E Escobedo / N Rubin | USA | USA | WC | 6-2 | 6-4 | | 1:25 (76-63) |
| Thu 03.02.20 | Kevin Krawietz / Andreas Mies | GER | GER | 6 | 2-1 | Max Purcell / Luke Saville | AUS | AUS | | 7-64 | 6-75 | 6-4 | 2:38 (120-116) |
| Thu 03.02.20 | Jamie Murray / Neal Skupski | GBR | GBR | | 2-0 | Ivan Dodig / Filip Polasek | CRO |  SVK | 4 | 6-3 | 7-5 | | 1:31 (68-54) |
| Thu 03.02.20 | Marcelo Demoliner / Matwe Middelkoop | BRA | NED | | 2-1 | Nicolas Mahut / Jan-Lennard Struff | FRA | GER | | 6-74 | 7-65 | 6-3 | 2:00 (105-95) |
| Thu 03.02.20 | Jack Sock / Jack Withrow | USA | USA | | 2-1 | Dominic Inglot / Aisam Ul-Haq Qureshi | GBR |  PAK | | 6-75 | 7-62 | 7-65 | 2:28 (119-109) |
| Wed 02.02.20 | Mate Pavic / Bruno Soares | CRO | BRA | | 2-1 | Marcel Granollers / Horacio Zeballos |  ESP | ARG | 5 | 3-6 | 6-4 | 6-4 | 2:02 (88-82) |
| Wed 02.02.20 | Marcus Daniell / Philipp Oswald | NZL | AUT | | 2-0 | Raven Klaasen / Oliver Marach |  RSA | AUT | 7 | 6-3 | 7-65 | | 1:41 (74-66) |
| Wed 02.02.20 | Christopher Eubanks / Mackenzie McDonald | USA | USA | WC | 2-0 | Luke Bambridge / Ben Mclachlan | GBR |  JPN | | 6-3 | 6-2 | | 1:13 (67-48) |
| Wed 02.02.20 | Christian Harrison / Ryan Harrison | USA | USA | WC | 2-1 | Jeremy Chardy / Fabrice Martin | FRA | FRA | | 5-7 | 7-65 | 7-5 | 2:30 (114-109) |
| Wed 02.02.20 | Rajeev Ram / Joe Salisbury | USA | GBR | 3 | 2-1 | Austin Krajicek / Franko Skugor | USA | CRO | | 6-2 | 6-75 | 6-3 | 1:58 (85-75) |
| Wed 02.02.20 | Wesley Koolhof / Nikola Mektic | NED | CRO | 8 | 2-1 | N Cacic / Divij Sharan |  SRB | IND | | 6-4 | 3-6 | 6-3 | 1:49 (81-85) |
| Wed 02.02.20 | Simone Bolelli / Maximo Gonzalez | ITA | ARG | | 2-0 | Santiago Gonzalez / Ken Skupski |  MEX | GBR | | 6-4 | 6-3 | | 1:41 (81-71) |
| Thu 03.02.20 | John Peers / Michael Venus | AUS | NZL | | 2-0 | N Lammons / Nicholas Monroe | USA | USA | WC | 6-4 | 6-2 | | 1:08 (61-47) |
| Wed 02.02.20 | Sander Gille / Joran Vliegen | BEL | BEL | | 2-0 | Lukasz Kubot / Marcelo Melo |  POL | BRA | 2 | 6-2 | 6-4 | | 1:25 (66-52) |
